Use and Abuse of Eis in Studying the Mechanisms of Co2/h2s Corrosion of Mild Steel

Electrochemical Impedance Spectroscopy (EIS) is a powerful transient technique which enables an insight into the corrosion process not easily obtained by other predominantly DC techniques. However the EIS technique presents a large challenge both from a theoretical as well as an experimental point of view. Collecting accurate EIS raw data is not easy as EIS is plagues with errors not seen by the DC techniques. Building mechanistic models to capture the EIS data is a very complex task which enables extraction of valuable information about the corrosion process, however the time and effort investment required is very large. In this study of CO2/H2S corrosion of mild steel it was found that a “minor” detail in the experimental set-up caused erroneous acquisition of EIS raw data. These data were “successfully” modeled by using a complex electrochemical theory, which appeared plausible. When the experimental mistake was discovered the EIS data were retaken, the analysis was redone and the conclusions about the corrosion process were completely revised.